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Temperatures below zero degree Celsius (that is, the minus scale) can be measured by resistance thermometers. They work on the premise that the resistance of materials changes with temperature. Resistance decreases as the temperature is reduced in the case of metals (positive temperature coefficient), while the resistance increases with decrease of temperature in the case of semiconductors (negative temperature coefficient). Platinum resistance thermometers are used down to minus 170 degree Celsius. For measurement of even lower temperatures, Germanium and Silicon diode (semiconductor) thermometers are used. Thermocouples can also be used for measuring temperatures below zero degrees
Source: thehindu.com